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Photocycle alteration and increased enzymatic activity in genetically modified photoactivable adenylate cyclase OaPAC

Archive ouverte | Raics, Katalin | CCSD

International audience. Photoactivated adenylate cyclases (PACs) are light activated enzymes that combine blue light sensing capacity with the ability to convert ATP to cAMP and pyrophosphate (PPi) in a light-depend...

Photochemical and Molecular Dynamics Studies of Halide Binding in Flavoenzyme Glucose Oxidase

Archive ouverte | Zhuang, Bo | CCSD

International audience. Glucose oxidase (GOX), a characteristic flavoprotein oxidase with widespread industrial applications, binds fluoride (F−) and chloride (Cl−). We investigated binding properties of halide inhi...

Photochemical processes in flavo-enzymes as a probe for active site dynamics: TrmFO of Thermus thermophilus

Archive ouverte | Zhuang, Bo | CCSD

International audience. Quenching of flavin fluorescence by electron transfer from neighboring aromatic residues is ubiquitous in flavoproteins. Apart from constituting a functional process in specific light-active ...

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