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Mn 2+ bispidine complex combining exceptional stability, inertness and MRI efficiency

Archive ouverte | Ndiaye, Daouda | CCSD

International audience. As an essential metal ion and an efficient relaxation agent, Mn 2+ holds great promise to replace Gd 3+ in MRI contrast agent applications, if its stable and inert complexation can be achieve...

A seven-coordinate Mn( ii ) complex with a pyridine-based 15-membered macrocyclic ligand containing one acetate pendant arm: structure, stability and relaxation properties

Archive ouverte | Pražáková, Marie | CCSD

International audience. A new 15-membered pyridine-based macrocyclic ligand containing one acetate pendant arm (N-carboxymethyl-3,12,18-triaza-6,9-dioxabicyclo[12.3.1]octadeca-1(18),14,16-triene, L1) was synthesized...

Structural Variations in Carboxylated Bispidine Ligands: Influence of Positional Isomerism and Rigidity on the Conformation, Stability, Inertness and Relaxivity of their Mn 2+ Complexes

Archive ouverte | Ndiaye, Daouda | CCSD

International audience. Mn 2+ complexes of 2,4‐pyridyl‐disubstituted bispidine ligands have emerged as more biocompatible alternatives to Gd 3+ ‐based MRI probes. They display relaxivities comparable to that of comm...

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